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Determination of Copper in Graphite Powder (Flame Atomic Absorption Spectrometry)

1. Method Overview

After the sample is digested with aqua regia, the determination is carried out using an air-acetylene flame at an instrument wavelength of 324.7 nm.

2. Instruments and Reagents

2.1 Instruments and Equipment

2.1.1 Testing Instruments

Serial No. 이름 수량 Technical Requirements 부속품
1 Flame Atomic Absorption Spectrophotometer 1 set Copper Hollow Cathode Lamp
2 Acetylene Gas 1 cylinder Purity ≥ 99.99%
3 Air Compressor 1 set Rated discharge pressure: 0.3 MPa

2.1.2 Sample Pretreatment Equipment

Serial No. 이름 수량 Technical Requirements 부속품
1 Temperature-Controlled Hot Plate 1 set Rated temperature: Room temperature ~ 300℃
2 Electronic Balance 1 set Sensitivity: 0.1 mg
3 Ultrapure Water System 1 set
4 Micropipette 1 each Ranges: 20 μL~200 μL, 100 μL~1000 μL
5 Volumetric Flask Several Volume: 100 mL
6 Test Tube Several Volume: 25 mL

2.2 Reagents

2.2.1 Raw Reagents

Serial No. 이름 Technical Requirements 발언
1 Nitric Acid MOS Grade
2 Hydrochloric Acid Guaranteed Reagent (GR)

2.2.2 Prepared Reagents

Serial No. 이름 Preparation Method 발언
1 Nitric Acid Solution (1+99) Measure 10 mL of nitric acid, slowly add it to 990 mL of deionized water, and mix well.

2.3 Reference Standards

2.3.1 Stock Solution

Serial No. No. 이름 Technical Requirements 발언
1 GBW 08615 Copper Single-Element Standard Solution Concentration: 1000 μg/mL National Institute of Metrology, China

3. Result Calculation

The copper content in the sample is calculated using the following formula:


어디:
  • X = Copper content in the sample, unit: milligram per kilogram (mg/kg);
  • ρ= Mass concentration of copper in the sample test solution, unit: microgram per milliliter (μg/mL);
  • ρ0= Mass concentration of copper in the blank solution, unit: microgram per milliliter (μg/mL);
  • 에프 = Dilution factor of the digested sample solution;
  • V = Total volume of the digested sample solution, unit: milliliter (mL);
  •  = Mass of the sample, unit: gram (g).

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