{"id":3914,"date":"2025-09-09T11:17:07","date_gmt":"2025-09-09T03:17:07","guid":{"rendered":"https:\/\/www.pgeneral.com\/?p=3914"},"modified":"2025-09-09T11:17:07","modified_gmt":"2025-09-09T03:17:07","slug":"determination-of-nickel-in-reflective-coating-of-mirrors-flame-atomic-absorption-spectrometry","status":"publish","type":"post","link":"https:\/\/www.pgeneral.com\/tr\/applications\/determination-of-nickel-in-reflective-coating-of-mirrors-flame-atomic-absorption-spectrometry","title":{"rendered":"Aynalar\u0131n Yans\u0131t\u0131c\u0131 Kaplamas\u0131nda Nikelin Belirlenmesi (Alev Atom Emme Spektrometrisi)"},"content":{"rendered":"

1. Y\u00f6ntem Genel Bak\u0131\u015f<\/h2>\n
\u00d6rnek \u00f6nceden i\u015flenildikten sonra, bir atomik emi\u015f spektrometri i\u00e7ine girer ve emi\u015fimi belirlemek i\u00e7in alev taraf\u0131ndan atomla\u015ft\u0131r\u0131l\u0131r. Belirli bir konsantrasyon aral\u0131\u011f\u0131nda, emici de\u011fer i\u00e7eri\u011fe orant\u0131l\u0131d\u0131r ve standart serilerle kar\u015f\u0131la\u015ft\u0131r\u0131larak miqdarl\u0131k yap\u0131l\u0131r.<\/div>\n
\n

2. Aletler ve Reagentler<\/h2>\n

2.1 Aletler ve Ekipmanlar<\/h3>\n

2.1.1 Test Aletleri<\/h4>\n
\n
\n\n\n\n\n\n\n\n
Seri numaras\u0131.<\/th>\n\u0130sim<\/th>\nMiktar<\/th>\nTeknik Gereksinimler<\/th>\nAksesuarlar<\/th>\n<\/tr>\n<\/thead>\n
1<\/td>\nAlev Atom Emme Spektrofotometri<\/td>\n1 set<\/td>\n–<\/td>\nNikel Bo\u015f Katod Lambas\u0131<\/td>\n<\/tr>\n
2<\/td>\nHava Kompres\u00f6r\u00fc<\/td>\n1 set<\/td>\nNominal bo\u015faltma bas\u0131nc\u0131: 0.3 MPa<\/td>\n–<\/td>\n<\/tr>\n
3<\/td>\nAsetilen Gaz\u0131<\/td>\n1 silindir<\/td>\nSafl\u0131k \u2265% 99,99<\/td>\n–<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n

2.1.2 \u00d6rnek \u00d6n Tedavi Ekipmanlar\u0131<\/h4>\n
\n
\n\n\n\n\n\n\n\n\n\n\n
Seri numaras\u0131.<\/th>\n\u0130sim<\/th>\nMiktar<\/th>\nTeknik Gereksinimler<\/th>\nAksesuarlar<\/th>\n<\/tr>\n<\/thead>\n
1<\/td>\nElektronik Denge<\/td>\n1 set<\/td>\nHassasiyet: 0.1 mg<\/td>\n–<\/td>\n<\/tr>\n
2<\/td>\nPolitetrafluoroetilen (PTFE) Ke\u015fekler<\/td>\nBirka\u00e7<\/td>\nHacim: 100 ml<\/td>\nPTFE bardak kapaklar\u0131 dahil<\/td>\n<\/tr>\n
3<\/td>\nAyarlanabilir S\u0131cak Plaka<\/td>\n1 set<\/td>\nS\u0131cakl\u0131k aral\u0131\u011f\u0131: Oda s\u0131cakl\u0131\u011f\u0131 ~ 300 \u2103<\/td>\n–<\/td>\n<\/tr>\n
4<\/td>\nMikropipetler<\/td>\nHer biri 1<\/td>\nHacim aral\u0131klar\u0131: 20 \u03bcL ~ 200 \u03bcL; 1000 \u03bcL ~ 5000 \u03bcL<\/td>\n–<\/td>\n<\/tr>\n
5<\/td>\nhacimli \u015fi\u015feler<\/td>\nBirka\u00e7<\/td>\nHacimler: 100 mL, 1000 mL<\/td>\n–<\/td>\n<\/tr>\n
6<\/td>\nKolorimetrik T\u00fcpler<\/td>\nBirka\u00e7<\/td>\nHacim: 25 ml<\/td>\n–<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n

2.2 Reagentler<\/h3>\n

2.2.1 Ham Reagentler<\/h4>\n
\n
\n\n\n\n\n\n
Seri numaras\u0131.<\/th>\n\u0130sim<\/th>\nTeknik Gereksinimler<\/th>\nNotlar<\/th>\n<\/tr>\n<\/thead>\n
1<\/td>\nNitrik Asit<\/td>\nMOS S\u0131n\u0131f\u0131<\/td>\n–<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n

2.2 Haz\u0131rlanan Reagentler<\/h4>\n
\n
\n\n\n\n\n\n
Seri numaras\u0131.<\/th>\n\u0130sim<\/th>\nHaz\u0131rlama Y\u00f6ntemi<\/th>\nNotlar<\/th>\n<\/tr>\n<\/thead>\n
1<\/td>\nNitrik Asit \u00c7\u00f6z\u00fcm\u00fc (1 99)<\/td>\n10 mL nitrik asit \u00f6l\u00e7\u00fcn, 990 mL suya ekleyin ve iyi kar\u0131\u015ft\u0131r\u0131n.<\/td>\n–<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n

2.3 Referans Standartlar\u0131<\/h3>\n

2.3.1 Stok \u00c7\u00f6z\u00fcm\u00fc<\/h4>\n
\n
\n\n\n\n\n\n
Seri numaras\u0131.<\/th>\n- Hay\u0131r. - Hay\u0131r.<\/th>\n\u0130sim<\/th>\nTeknik Gereksinimler<\/th>\nNotlar<\/th>\n<\/tr>\n<\/thead>\n
1<\/td>\nGBW08618 Hakk\u0131nda<\/td>\nNikel Tek Elemanl\u0131 Standart \u00c7\u00f6z\u00fcm<\/td>\nKonsantrasyon: 1000 \u03bcg \/ mL<\/td>\nUlusal Metroloji Enstit\u00fcs\u00fc, \u00c7in<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n

3. Operasyon Prosed\u00fcr\u00fc<\/h2>\n

3.1 \u00d6rnek Haz\u0131rlama<\/h3>\n

3.1.1 Test \u00c7\u00f6z\u00fcm\u00fcn\u00fcn Haz\u0131rlanmas\u0131<\/h4>\n
\u00d6rnek \u00d6n Tedavi:
T\u00fcm aynan\u0131, yans\u0131t\u0131c\u0131 taraf\u0131n yukar\u0131ya bakan bir PTFE barda\u011f\u0131na yerle\u015ftirin. 1 ml su ve 5 ml nitrik asit ekleyin (s\u0131v\u0131 seviyesi aynan\u0131n yans\u0131t\u0131c\u0131 y\u00fczeyini tamamen kaplamal\u0131d\u0131r). Kafeyi kapat\u0131n, aynan\u0131n yans\u0131t\u0131c\u0131 kaplamas\u0131 tamamen kaybolana kadar sindirim i\u00e7in 1 saat \u0131s\u0131t\u0131n. Kafeyi \u00e7\u0131kar\u0131n, so\u011futun, \u00e7\u00f6z\u00fcm\u00fc 25 mL kolorimetrik t\u00fcpte i\u015faretlenmi\u015f hacime seyreltin, iyi sallay\u0131n ve depolama i\u00e7in plastik bir \u015fi\u015feye aktar\u0131n. Ayn\u0131 anda bo\u015f bir \u00f6rnek haz\u0131rlay\u0131n.<\/div>\n

3.1.2 Standart \u00c7\u00f6z\u00fcmlerin Haz\u0131rlanmas\u0131<\/h4>\n
Nikel Standart Serisinin Haz\u0131rlanmas\u0131:
Pipet 0 mL, 25 \u03bcL, 50 \u03bcL, 100 \u03bcL ve 150 \u03bcL nikel standart \u00e7\u00f6z\u00fcm\u00fc (1000 \u03bcg\/mL) s\u0131ras\u0131yla 100 mL hacimli \u015fi\u015felere. Nitrik asit \u00e7\u00f6z\u00fcm\u00fc ile i\u015faretlenmi\u015f hacime seyreltin (99) ve iyi kar\u0131\u015ft\u0131r\u0131n. Bu standart serinin konsantrasyonlar\u0131 \u015funlard\u0131r: 0 \u03bcg\/mL, 0.25 \u03bcg\/mL, 0.50 \u03bcg\/mL, 1.00 \u03bcg\/mL ve 1.50 \u03bcg\/mL.<\/div>\n

3.2 \u00d6rnek Testi<\/h3>\n
    \n
  1. Test Ko\u015fullar\u0131
    Alev Atomik Emme Spektrofotometri Tespiti i\u00e7in Referans Ko\u015fullar\u0131<\/li>\n<\/ol>\n


    <\/p>\n

    \n
    \n\n\n\n\n\n\n\n\n\n\n
    Parametre<\/th>\n\u00d6zellikler<\/th>\n<\/tr>\n<\/thead>\n
    Dalga Uzunlu\u011fu<\/td>\n232.0 nm'lik<\/td>\n<\/tr>\n
    Spektral Bant Geni\u015fli\u011fi<\/td>\n0,1 nm'lik<\/td>\n<\/tr>\n
    Element Lamba Ak\u0131m\u0131<\/td>\n4.0 mA'l\u0131k<\/td>\n<\/tr>\n
    Yan\u0131c\u0131 Y\u00fcksekli\u011fi<\/td>\n6 mm'lik<\/td>\n<\/tr>\n
    Yak\u0131t Gaz\u0131 Ak\u0131\u015f H\u0131z\u0131<\/td>\n1300 ml \/ dakika<\/td>\n<\/tr>\n
    Hava Kompres\u00f6r\u00fc Bas\u0131nc\u0131<\/td>\n0,22 MPa'n\u0131n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n


    <\/p>\n

      \n
    1. \u00d6rnek testi
      Aleti optimal \u00e7al\u0131\u015fma durumuna ayarlay\u0131n ve suyla s\u0131f\u0131rlay\u0131n. Standart \u00e7\u00f6z\u00fcmlerin, bo\u015f test \u00e7\u00f6z\u00fcm\u00fcn\u00fcn ve test \u00e7\u00f6z\u00fcm\u00fcn\u00fcn emilimini s\u0131ras\u0131yla belirleyin.<\/li>\n<\/ol>\n


      <\/p>\n

      S\u0131f\u0131r standart \u00e7\u00f6z\u00fcm\u00fcn emilimini her standart \u00e7\u00f6z\u00fcm\u00fcn emiliminden \u00e7\u0131kar\u0131n. K\u00fctle konsantrasyonu (\u03bcg\/mL) absisa olarak ve ilgili emici ordinat olarak bir \u00e7al\u0131\u015fma e\u011frisi \u00e7izin. Test \u00e7\u00f6z\u00fcm\u00fcn\u00fcn \u00f6l\u00e7\u00fclen emilmesine dayanarak, \u00e7al\u0131\u015fma e\u011frisinden nikel k\u00fctle konsantrasyonunu bulun.<\/div>\n<\/div>","protected":false},"excerpt":{"rendered":"

      1. Method Overview After the sample is pretreated, it is introduced into an atomic absorption spectrometer and atomized by flame to determine the absorbance. Within a certain concentration range, the absorbance value is proportional to the content, and quantification is performed by comparison with the standard series. 2. Instruments and Reagents 2.1 Instruments and Equipment […]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[81,36],"tags":[],"class_list":["post-3914","post","type-post","status-publish","format-standard","hentry","category-petrochemical-and-chemical","category-applications"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/posts\/3914","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/comments?post=3914"}],"version-history":[{"count":0,"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/posts\/3914\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/media?parent=3914"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/categories?post=3914"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.pgeneral.com\/tr\/wp-json\/wp\/v2\/tags?post=3914"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}